The partition functions of JANAF polyatomic molecules that significantly affect the stellar atmospheric equation of state

Statistics – Computation

Scientific paper

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Cool Stars, Equations Of State, Partitions (Mathematics), Polyatomic Molecules, Stellar Atmospheres, Computational Astrophysics, Least Squares Method, Stellar Composition

Scientific paper

Least square polynomial fits to polyatomic partition functions are presented which are mostly obtained from the revised JANAF thermochemical tables (Chase et al., 1985). The maximum importance of each polyatomic has been calculated based upon equation of state calculations on a grid of temperatures from 1000-6000 K, pressures from 0.1 to 10 to the 6th Pa, M/H abundance ratio values from -2 to 1, and C/O abundance ratio values from 0 to 1. It is noted that the present data, providing the polyatomic information necessary to calculate the equation of state of cool stellar atmospheres, is subject to systematic errors resulting from incomplete spectroscopic information.

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