Other
Scientific paper
Nov 1980
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1980gecoa..44.1801g&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 44, Issue 11, pp.1801-1810
Other
Scientific paper
Analyses of two Tertiary fossil resins and a Tertiary montan wax have revealed the presence of a number of sesquiterpenoids. Using gas chromatographic retention data obtained on both polar and non-polar stationary phases and mass spectral comparisons with authentic compounds, the sesquiterpenoids -cedrene, cedrane, cuparene, cedren-10-one, 8 H cedran-9-one and cuparenic acid have been identified in the fossil resin retinellite and a montain wax (both Oligocene) from lignite beds in the Bovey basin of Devon, England, and in the Pliocene fossil resin ionite from the lone valley of California. U.S.A. The sesquiterpenoids -cedrene, cuparene and cuparenic acid are characteristic constituents of the essential oils of the Cupressaceae , a family of trees and shrubs of the order Coniferales , and it is argued that these fossil resins, and the montan wax, were derived from older forms of this family of plants. The ketones cedren-10-one and 8 H cedran-9-one, and the saturated hydrocarbon cedrane, are not reported to be constituents of modern genera of Cupressaceae and may have been formed during diagenesis. The cedrane occurring in these deposits appears to be a chemical hydrogenation product of -cedrene. The ketones, on the other hand, may have resulted from the oxidation of -cedrene although the mechanism of these reactions is not clear. If the ketones are not undetected constituents of these plants, then the presence in these deposits of both oxidised and fully-reduced -cedrene products infers that separate phases of oxidation and reduction occurred during the diagenesis of the fossil resins and the montan wax.
Douglas A. G.
Grantham P. J.
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