The isotopic compositions and concentrations of lead in some chondritic stone meteorites

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Microgram quantities of lead were volatilized from the chondrites Richardton, Holbrook, Beardsley and Plainview and purified for mass spectrometric analysis. Aliquots of approximately 1 g were surface-ionized by use of the boric acid technique. The isotopic compositions found range from highly radiogenic lead in the case of Richardton to leads in the other three chondrites which are substantially less radiogenic than average lead in the crust of the earth. p]From our recent concentration determinations by the isotopic dilution method, it seems that the amount of lead in Beardsley is about 0·13 p.p.m. and that in Richardton about 0·06 p.p.m. The leads in these meteorites are consistent within a factor of approximately two with the lead-lead ages and the independently measured uranium and thorium concentrations. The lead--lead age for Richardton is the same as that found by (1955) for Nuevo Laredo, being 4·6 Æ || . The lead concentration measured for Forest City is 0·09 p.p.m., while that for Holbrook is 0·28 p.p.m. Holbrook is quite anomalous in containing 2·5 times the amount of radiogenic lead that can be explained by the accumulation of decay products in situ with a primeval lead which had the isotopic composition of the lead from the troilite in the Canyon Diablo and Henbury iron meteorites. p]The total amount of lead on the surface of a meteorite appears to be comparable to the total amount inside. The isotopic composition of this surface lead indicates that it is principally terrestrial lead.

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