The isolation and identification of gamma-lactones in the acidic fraction in Aleksinac (Yugoslavia) shale bitumen

Computer Science

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Scientific paper

Gas chromatography-mass spectrometry-computer assisted analysis of the acidic fraction of Miocene Aleksinac shale bitumen (26 million years old) has shown a great variety of organic compounds. Samples obtained from both benzene and benzene-methanol extracts were investigated and found to contain a homologous series of -lactones (C 7 -C 15 ). These lactones possibly represent the only indication of unsaturated acids present during the shales deposition. In addition to the -lactones, straight chain aliphatic monocarboxylic acids (C 6 -C 12 ), dicarboxylie acids (C 6 -C 19 ), as well as many aromatic acids have been detected.

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