The heterogeneous reaction of HOCl + HCl - Cl2 + H2O on ice and nitric acid trihydrate - Reaction probabilities and stratospheric implications

Details The heterogeneous reaction of HOCl + HCl - Cl2 + H2O on ice and nitric acid trihydrate - Reaction probabilities and stratospheric implications The heterogeneous reaction of HOCl + HCl - Cl2 + H2O on ice and nitric acid trihydrate - Reaction probabilities and stratospheric implications

Mar 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992georl..19..461a&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 19, March 3, 1992, p. 461-464.

Mathematics

Probability

58

Atmospheric Chemistry, Chlorine Compounds, Hydrochloric Acid, Ice, Nitric Acid, Stratosphere, Chemical Reactions, Chlorine, Hydrates, Water

Scientific paper

Studies of the heterogeneous reaction HOCl + HCl - Cl2(g) + H2O(s) on ice and on nitric acid trihydrate (NAT) surfaces are reported. The reaction probability on a NAT surface as a function of its H2O vapor pressure is reported for the first time. At a given temperature, this parameter can be used to characterize uniquely the NAT surface and to distinguish it from ice/NAT mixtures. Alternatively, the HNO3 vapor pressure can be used, but it is more difficult to monitor.

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