The Gas Phase Spectrum of Cyclic C18 and the Diffuse Interstellar Bands

Astronomy and Astrophysics – Astronomy

Scientific paper

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Ism: General, Ism: Lines And Bands, Ism: Molecules, Stars: Individual (Ζ Oph), Stars: Individual: Henry Draper Number: Hd 204827

Scientific paper

The gas phase spectrum of the cyclic C18 molecule recorded in the laboratory at a temperature typical of diffuse interstellar clouds is compared with absorption features toward ζ Oph and HD 204827 in the 5730-5934 Å region. For the origin band at 5928.5 Å an upper limit to the column density of <=1.8×1011 cm-2 is inferred. The origin band pattern in the laboratory spectrum changes on lowering the internal temperature in the 100-20 K range and bears a striking resemblance to the observed structure of a number of DIBs at other wavelengths. This suggests that platelike molecules or ions, comprising a couple of dozen to hundred carbon atoms, could be responsible for some of the latter absorptions.

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