The formation of SiH+, PH+, and SH+ by radiative association

Details The formation of SiH+, PH+, and SH+ by radiative association The formation of SiH+, PH+, and SH+ by radiative association

Feb 2000

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000a%26as..142..107s&link_type=abstract

Astronomy and Astrophysics Supplement, v.142, p.107-112

Astronomy and Astrophysics

Astrophysics

3

Molecular Processes, Ism: Molecules

Scientific paper

Cross sections for the radiative association of Si+, P+, and S+ with atomic hydrogen to form the diatomic molecular ions SiH+, PH+, and SH+, respectively, are presented. The results are obtained using fully quantum-mechanical techniques and utilize ab initio molecular data calculated with the multireference single- and double-excitation configuration-interaction (MRD-CI) method. Thermal rate coefficients are presented and applications of the results to diffuse interstellar clouds are discussed.

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