Astronomy and Astrophysics – Astronomy
Scientific paper
Mar 1996
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996mnras.279..591d&link_type=abstract
Monthly Notices of the Royal Astronomical Society, Volume 279, Issue 2, pp. 591-594.
Astronomy and Astrophysics
Astronomy
25
Molecular Processes, Ism: Abundances, Dust, Extinction, Ism: Molecules
Scientific paper
A model for H_2 formation by reaction of H-atoms with the surface of carbonaceous grains is developed. Such reactions, which involve interstitial H-atoms at low grain temperature and H-atoms bonded to -CH, -CH_2 and -CH_3 groups at higher temperature, occur promptly on the collision of an H-atom with a grain surface. The rate of hydrogen formation and the efficiency of reaction depend on both gas kinetic and dust temperature. The rate coefficient R (cm^3 s^-1) for H_2 formation using this prompt-reaction model (PRM) can be calculated from laboratory data and is consistent with measured values of R. The dependence of R on ambient conditions in interstellar clouds can be easily estimated from this prompt-reaction model. R is found to be strongly dependent on gas kinetic temperature T_k and can exceed 10^-17 cm^3 s^-1, even for warm dust, when T_k>~300 K.
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