Other
Scientific paper
Nov 2005
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2005gecoa..69.4971v&link_type=abstract
Geochimica et Cosmochimica Acta, Volume 69, Issue 21, p. 4971-4984.
Other
5
Scientific paper
The composition and temperature of vent fluids sampled from the active hydrothermal system in Escanaba Trough, Gorda Ridge in 2000 and 2002 remain unchanged from the only time this field was previously sampled, in 1988. ODP Leg 169 drilled nine bore holes at this site in 1996, some within meters of the vents, yet this disturbance has not impacted the measured compositions or temperatures of the fluids exiting at the seafloor. The fluids have maximum measured temperatures of 218°C and contain ˜20% more chloride than local ambient seawater. Our interpretation is that the fluid compositions are generated by supercritical phase separation of seawater, with much of the water-rock reaction occurring within the ˜400m thick sedimentary section that overlies the basalt at this site. The ODP drilling results provide information on the mineralogy and composition of materials below the seafloor, as well as direct constraints not typically available on the physical conditions occurring below the seafloor hydrothermal system. Calculations utilizing geochemical modeling software suggest the fluids are close to saturation with a suite of minerals found subsurface, suggesting equilibrium between the fluids and substrate. These results provide an explanation for why the fluids have remained chemically stable for 14 yrs. The pore water data from drilling suggest that the hydrology and chemistry of the hydrothermal system are much more complex within the sediment cover than would be expected from the surface manifestations of the hydrothermal system. While the pore waters have chloride contents both greater and less than the local seawater, only fluids with higher chloride contents vent at the seafloor. Our calculations suggest that at the current conditions the “brines” (fluids with chlorinity greater than seawater) are actually less dense than the “vapors” (fluids with chlorinity less than seawater). These density relationships may provide an explanation for why the “brines” are now venting preferentially to the “vapors,” a situation opposite to what is usually observed or inferred.
Clague David A.
Lilley Deloris M.
McClain James S.
Olson Eric J.
Parker Michael C.
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