The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals

Details The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confetj06y&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Electronic

Scientific paper

Laser-induced fluorescence (LIF) and single vibronic level (SVL) emission spectra of the Ã^{2}Π_u-X˜^{2}A_1 transitions of the jet-cooled boron difluoride (BF_2) and boron dichloride (BCl_2) radicals have been observed. In each case, the radical was produced in a pulsed discharge jet using a precursor mixture of the corresponding boron halide (BF_3 or BCl_3) in high pressure argon. Due to a large change in geometry from a bent ground state to a linear excited state, the LIF spectra are very extensive and the emission spectra show long bending progressions. Strong LIF bands of ^{11}BF_2 and ^{10}BF_2 (from isotopically enriched ^{10}BF_3) were observed in the 29200-35100 cm^{-1} region and isotope shifts were identified. The rotational constants obtained from high resolution LIF spectra of the two isotopologues were used to determine the effective zero-point structure of the ground state. For BCl_2, weaker and much more complex LIF spectra, which have as yet defied vibrational analysis, were recorded in the 15300-22700 cm^{-1} region. SVL emission spectra of five isotopologues have been obtained, affording a detailed vibrational analysis of the ground state of BCl_2.

Affiliated with

Also associated with

No associations

Rating

The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and The Electronic Spectra of the Jet-Cooled Boron Difluoride (BF_2) and Boron Dichloride (BCl_2) Free Radicals will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1642829