The dissociation energy of the CN radical determined from the CN internal energy release of the C + NO yielding CN + O reaction

Details The dissociation energy of the CN radical determined from the CN internal energy release of the C + NO yielding CN + O reaction The dissociation energy of the CN radical determined from the CN internal energy release of the C + NO yielding CN + O reaction

Jun 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990a%26a...232..270c&link_type=abstract

Astronomy and Astrophysics (ISSN 0004-6361), vol. 232, no. 1, June 1990, p. 270-276.

Astronomy and Astrophysics

Astrophysics

40

Cosmochemistry, Cyanogen, Free Radicals, Gas Dissociation, Late Stars, Nitrogen, Carbon, Laser Induced Fluorescence, Molecular Beams, Reaction Products

Scientific paper

The reaction between C and NO yielding CN and O, produced by crossing two pulsed molecular beams of C and NO, is studied by probing the nascent unrelaxed CN(X2Sigma/+/) product at the crossing point with the laser-induced fluorescence technique. An experimental value of D(0)(CN) = 7.77 + or - 0.05 eV was determined, which is higher than the value 7.65 + or - 0.06 eV, derived by Bauschlicher et al. (1988) from ab-initio calculations.

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