Temperature dependence of self broadening of ammonia transitions in the ν2 band.

Details Temperature dependence of self broadening of ammonia transitions in the ν2 band. Temperature dependence of self broadening of ammonia transitions in the ν2 band.

Jun 1995

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1995jqsrt..53..671b&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 53, issue 6, pp. 671-680

Computer Science

6

Ammonia: Line Broadening, Ammonia: Infrared Lines

Scientific paper

Self broadening coefficients have been measured as a function of temperature from 192 to 377 K for five transition lines of the ν2 band of ammonia at ≡937 cm-1. The results have been compared with theoretical calculations performed in the semiclassical impact approximation, and although one hot transition does not fit well in this scheme, there is in general a fairly good agreement. Moreover there is also an experimental and theoretical evidence against the commonly assumed power law for the temperature dependence.

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