Temperature and perturber dependences of water vapor line-broadening - Experiments at 183 GHz; calculations below 1000 GHz

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Atmospheric Composition, Molecular Gases, Spectral Line Width, Temperature Dependence, Water Vapor, Extremely High Frequencies, Perturbation Theory, Submillimeter Waves

Scientific paper

Measurements of linewidths of the 3(13)-2(20) H2O line at 183 GHz are presented. These include broadening by H2O, N2, O2, and Ar with the temperature dependence in the 300-390 K range. The room-temperature experiments are in good agreement with previous results. Systematic calculations of H2O line-broadening parameters of lines centered below 1000 GHz are also presented. These have been performed for a recently developed and successfully tested model. Tabulations of the room-temperature values and temperature dependence for self-, N2-, O2-, air-, and CO2-broadening are given. These data should be useful for spectral calculations required by atmospheric applications.

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