Synchrotron powered FT-IR microspectroscopy permits small spot ATR sampling of fiber finish and other materials

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Organic Compounds, Polymers

Scientific paper

The absence of thermal noise, the nondivergence, and brightness of synchrotron radiation for FT-IR microspectroscopy permit aperturing the beam entering the ATR objective to less than the 100 μm diameter pattern usually used. With a ZnSe crystal, the 100 μm aperture produces a 42 μm spot of optical contact with the specimen. With synchrotron radiation, excellent S/N with smaller apertures permits spatially resolved probing of adjacent small spots along a specimen to reveal heterogeneity in the surface chemistry.

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