Surface effect on the isotopic fractionation between CO 2 and some carbonate minerals

Details Surface effect on the isotopic fractionation between CO 2 and some carbonate minerals Surface effect on the isotopic fractionation between CO 2 and some carbonate minerals

May 1974

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974gecoa..38..669h&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 38, Issue 5, pp.669-681

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The surface effect on the isotopic fractionation between CO 2 and calcite, dolomite and witherite has been studied through gas-solid exchange experiments. Oxygen isotope fractionation between surface calcite and CO 2 was found to be higher by 5-6%. than the fractionation between bulk calcite and CO 2 . Similar studies were made using dolomite and witherite. The dolomite-calcite and witheritecalcite fractionation evaluated through the surface exchange with CO 2 were found to be close to values determined by other workers under controlled conditions in the laboratory.

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