Sulfur Chemistry in K/T-Sized Impact Vapor Clouds

Mathematics – Logic

Scientific paper

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Vapors, Clouds (Meteorology), Sulfur, Chemical Reactions, Cretaceous-Tertiary Boundary, Guy Wires, Hypervelocity Impact, Irradiation, Kinetics, Laser Outputs, Spectroscopic Analysis, Sulfur Dioxides, Sulfuric Acid

Scientific paper

The geologic record indicates that the mass extinction at K/T boundary, 65 Myrs ago, was caused by a hypervelocity impact of an asteroid or a comet. During the K/T impact event, a large amount of sulfur was degassed from the impact site. The degassed sulfur converts to sulfuric acid aerosol and stays in the stratosphere for a long time. This reduces the sunlight significantly and leads to a mass extinction. However, if the degassed sulfur is dominated by SO3 not SO2, then the conversion to sulfuric acid aerosol occurs very rapidly and the blockage of sunlight does not last for a long time. The chemical reaction of sulfur-oxides in an impact vapor cloud, nevertheless, has not been studied in detail previously, and the SO2/SO3 ratio in a vapor cloud is yet highly uncertain. The purpose of this study is to estimate the SO2/SO3 ratio in the K/T impact vapor cloud. Here we discuss the results of calculation of chemical equilibrium and kinetics of sulfur-containing species in an impact vapor cloud as well as mass spectroscopic analysis of vapor plumes created by laser irradiation on anhydrite.

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