Stratospheric transport by stationary planetary waves - The importance of chemical processes

Mathematics – Logic

Scientific paper

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Atmospheric Chemistry, Atmospheric Circulation, Planetary Waves, Stratosphere, Transport Properties, Photochemical Reactions, Sensitivity, Trace Elements

Scientific paper

The transport of reactive trace gases by stationary planetary scale waves was studied using the Matsuno wave model (1970) and the linear eddy equation based on the tracer continuity expression. It is shown that K-theory fields become matrix fields when photochemical coupling effects are applied. The eddy flux of a trace gas is related to mean concentration gradients of other chemically coupled trace gases. The effects of photochemical coupling on eddy fluxes are determined for chemical processes involving the pairs O3 and NO(x) and NO and NO2. It was concluded that the influence of dynamical and chemical contributions to the uncoupled K-fields are different for various species indicating the source of error in 1- and 2-dimensional models.

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