Stratospheric heavy ozone - The symmetric isomer

Details Stratospheric heavy ozone - The symmetric isomer Stratospheric heavy ozone - The symmetric isomer

Nov 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992p%26ss...40.1573m&link_type=abstract

Planetary and Space Science (ISSN 0032-0633), vol. 40, no. 11, p. 1573-1579.

Other

6

Isomers, Mass Spectrometers, Oxygen Atoms, Oxygen 18, Ozone, Stratosphere, Earth Atmosphere, Ground State, Monte Carlo Method, Symmetry

Scientific paper

Flips in which one of the end atoms of an energized complex like (0-16)(0-16)(0-18)* ceases to be effectively bound to the central atom and becomes effectively bound to the other end atom (so that 0-18 is transformed into the central atom) are considered. Using the Monte Carlo method to follow the motion of three oxygen atoms on the ground state potential energy surface of ozone it is shown that the flips do indeed occur; and it is shown that their frequency relative to the dissociation frequency is consistent with the results of measurements by Anderson, et al. (1989).

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