Sticking coefficients for atoms and molecules at the surfaces of interstellar dust grains

Astronomy and Astrophysics – Astronomy

Scientific paper

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Adsorption, Cosmic Dust, Interstellar Chemistry, Interstellar Matter, Quantum Mechanics, Surface Reactions, Atomic Interactions, Chemisorption, Graphite, Lattice Parameters, Molecular Interactions, Phonons, Silicates

Scientific paper

A fully quantum mechanical model of the particle-surface sticking process is developed, and calculations are performed for a variety of atoms, molecules and solids of relevance to the interstellar medium. The sticking coefficient is a sensitive function of the nature of the particle-surface interaction and the lattice phonon spectrum. Soft lattices and/or chemical adsorption ensure high sticking coefficients. For hard lattices and physical adsorption, sticking is unlikely to occur. The consequences for surface reactions in the interstellar medium are briefly discussed.

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