Status on the Global Vibration-Rotation Model in Acetylene

Statistics – Applications

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Infrared/Raman

Scientific paper

We have developed a global model to deal with all vibration-rotation levels in acetylene up to high vibrational excitation energy, typically up to 9000 wavenumbers. It has been applied to a number of isotopologues, considering all known vibration-rotation lines published in the literature, for various purposes such as line assignment and astrophysical applications. Coriolis interaction is now systematically being introduced in the model. Recent results concerning the analysis of hot emission FTIR spectra recorded around 3 microns by R. Georges et al. at the University of Rennes (France) and of CW-CRDS spectra recorded around 1.5 microns by A. Campargue et al. at the University of Grenoble (France) will help illustrate the role of this vibration-rotation coupling in the global polyad scheme.
S. Robert, M. Herman, A. Fayt, A. Campargue, S. Kassi, A. Liu, L. Wang, G. Di Lonardo, and L. Fusina, Mol. Phys., 106, 2581 (2008).
A. Jolly, Y. Benilan, E. Cané, L. Fusina, F. Tamassia, A. Fayt, S. Robert, and M. Herman, J.Q.S.R.T., 109, 2846 (2008).

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