Stable Isotope Laser Spectrometer for Exploration of Mars

Details Stable Isotope Laser Spectrometer for Exploration of Mars Stable Isotope Laser Spectrometer for Exploration of Mars

Feb 1998

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998p%26ss...46..805s&link_type=abstract

Planetary and Space Science, vol. 46, p. 805

Biology

3

Tunable Lasers, Laser Spectrometers, Soil Sampling, Miniaturization, Mass Spectroscopy, Gas Analysis, Carbon Isotopes, Activity (Biology), Viking Lander Spacecraft, Stability, Rocks, Prototypes, Optical Paths, Mars Missions, Life Sciences, Geology

Scientific paper

On Earth, measurements of the ratios of stable carbon isotopes have providet much information about geological and biological processes. For example, fractionation of carbon occur in biotic processes and the retention of a distinctive 2-4% contrast in C-13/C-12 between organic carbon and carbonates in rocks as old as 3.8 billion years constitutes some of the firmest evidence for the antiquity of life on the Earth. We have developed a prototype tunable diode laser spectrometer which demonstrates the feasibility of making accurate in situ isotopic ratio measurements on Mars. This miniaturized instrument, with an optical path length of 10 cm should be capable of making accurate C-13/C-12 and N-15/N-14 measurements. Gas samples for measurement are to be produced by pyrolysis using soil samples as small as 50 mg. Measurements of C-13/C-12, O-18/O-16 and N-15/N-14 have been made to a precision of better than 0.1%, and various other isotopes are feasible. This laser technique, which relies on the extremely narrow emission linewidth of tunable diode lasers (less than 0.001/ cm),has favorable features in comparison to mass spectrometry, the standard method of accurate isotopic ratio measurement. The miniature instrument could be ready to deploy c 2003 or other Mars lander missions.

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