Spontaneous radiative properties of the excited electronic states of TiO

Details Spontaneous radiative properties of the excited electronic states of TiO Spontaneous radiative properties of the excited electronic states of TiO

Aug 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jqsrt..48..147s&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 48, no. 2, Aug. 1992, p. 147-152.

Computer Science

10

Electron States, Molecular Spectra, Radiative Transfer, Spontaneous Emission, Titanium Oxides, Forbidden Transitions, M Stars, Stellar Spectra, Wave Functions

Scientific paper

Ab initio electronic wavefunctions have been used to calculate and interpret absolute transition probabilities and oscillator strengths for all of the transitions involving the observed valence states of TiO. Spontaneous radiative lifetimes have been derived from the calculated probabilities and compared to related experimental data. The transitions are shown to be primarily atomically-forbidden transitions allowed in the molecule by orbital polarization.

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