Spectroscopy and nuclear spin conversion of a molecule of astrophysical interest in rare gas matrices : methane

Astronomy and Astrophysics – Astrophysics

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Scientific paper

Many hydrogenated species observed in space in cold media, exist in different nuclear spin configurations. In cometary's atmospheres and in interstellar molecular clouds, the relative populations of these 'nuclear spin isomers' deviate significantly from the thermal equilibrium. Experimental studies are therefore required to understand the parameters governing the nuclear spin enrichment and conversion in astrophysical conditions, especially in presence of ice. We present new experimental results of the nuclear spin conversion dynamics for CH_4 trapped in rare gas matrices between 4K and 20K. Results revealed for methane are compared to those obtained with water.

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