Computer Science
Scientific paper
Feb 1981
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1981gecoa..45..269s&link_type=abstract
Geochimica et Cosmochimica Acta, vol. 45, Issue 2, pp.269-272
Computer Science
Scientific paper
On the basis of a lack of Mössbauer evidence and of a vague interpretation of some i.r. absorptions, et al . (1979) conclude that no iron directly bound to humic materials persists after the usually accepted extraction and separation procedures. Many statements in the paper by et al . (1979) appear to be contradictory with this conclusion. In this comment the author has tried to demonstrate that Mössbauer spectroscopy alone cannot give an answer to the problem, but needs further spectroscopic and chemical evidence. Mössbauer data, overinterpreted by et al . (1979). have been critically discussed, in comparison with similar data previously obtained by various authors. Large spectroscopic--mainly Mössbauer, ESR and i.r.--evidence have been given in order to demonstrate the already well ascertained existence of organically bound iron in natural and synthetic complexes with humic substances.
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