Spectral absorption coefficients for the fundamental and first overtone vibration-rotation bands of CN

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Absorptance, Cn Emission, Free Radicals, Spectral Bands, Stellar Spectra, Harmonics, Molecular Oscillations, Molecular Rotation, Transition Probabilities

Scientific paper

A previous measurement of the transition moment of the fundamental vibration-rotation band of CN is combined with theoretical calculations of relative vibrational transition probabilities in order to compute absorption coefficients for the CN fundamental and first-overtone bands. Line strengths for 121 lines in each branch of all fundamental and first-overtone bands with upper-transition states not greater than 6 are calculated for temperatures of 2000, 3000, and 4000 K; these line strengths are presented as averaged over 8-kayser intervals. The relative vibrational transition moments are placed on an absolute scale, and the wavenumbers of the band origins and heads are given

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