Shock Vaporization of Anhydrite and Calcite and the Effect on Global Climate from K/T Impact Crater at Chicxulub

Computer Science

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Climate, Craters, Impacts, Shock, Vaporization

Scientific paper

The dominance of calcium sulfate minerals (anhydrite and gypsum) and calcium carbonate (calcite) in the upper 3 km of the Chicxulub section has prompted active research on the effects of their devolatilization upon impact. We present new data of vaporization criteria for anhydrite and calcite, the amount of S and C degassed during the Chicxulub impact and their effects on the global climate based on shock wave experiments, numerical simulation and thermodynamic calculations. The incipient and complete vaporization pressures are 81 +/- 7 GPa and 155 +/- 13 GPa for crystal anhydrite and the incipient and complete vaporization pressures are 54 +/- 6 GPa and 103 +/- 12 GPa for calcite crystal. About 3-20 x 10^16 gm carbon and 4-36 x 10^16 gm sulfur were degassed into the atmosphere due to the Chicxulub bolide. The global warming caused by the degassed CO2 is 0.2 degrees - 1.1 degrees C and the global cooling introduced by the degassed SO2 is 8.5 degrees - 16 degrees C.

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