Segmental Order and Dynamics of Polymer Networks Using Dipolar Correlation Effect Measured in Low Field NMR

Details Segmental Order and Dynamics of Polymer Networks Using Dipolar Correlation Effect Measured in Low Field NMR Segmental Order and Dynamics of Polymer Networks Using Dipolar Correlation Effect Measured in Low Field NMR

Apr 2007

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2007aipc..899..561m&link_type=abstract

SIXTH INTERNATIONAL CONFERENCE OF THE BALKAN PHYSICAL UNION. AIP Conference Proceedings, Volume 899, pp. 561-561 (2007).

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Molecular Dynamics And Other Numerical Methods, Correlation Times In Molecular Dynamics, Nuclear Resonance And Relaxation, Macromolecules And Polymer Molecules

Scientific paper

A new method for measuring the dipolar correlation function (DCF) based on the mixed magic- Hahn echoes decays has been implemented in inhomogeneous magnetic fields of NMR-MOUSE®. The Hahn echo will eliminate the contribution of the linear spin interactions like the inhomogeneities of the magnetic field. Segmental order and chain dynamics were studied in a series of natural rubber sample with different cross-link densities. The 1H residual second van Vleck moment and the correlation time were determined and correlated with the network properties.

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