Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N

Details Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N

2008-11-07

arxiv.org/abs/0811.1096v1

Astronomy and Astrophysics

Astrophysics

Scientific paper

10.1051/0004-6361:200810889

Ethyl cyanide is an abundant molecule in hot molecular clouds. Lines from 13C isotopically substituted ethyl cyanide were identified in Orion. To enable the search and the possible detection of other isotopologues of ethyl cyanide in interstellar objects, we have studied the rotational spectrum of deuterated ethyl cyanide: CH2DCH2CN (in-plane and out-of-plane) and CH3CHDCN and the spectrum of15N substituted ethyl cyanide CH3CH2C15N. The rotational spectrum of each species in the ground state was measured in the microwave and millimeter-submillimeter wavelength range using a waveguide Fourier transform spectrometer (8 - 17 GHz) and a source-modulated spectrometer employing backward-wave oscillators (BWOs) (150 - 260 and 580 - 660 GHz). From the fitting procedure, accurate spectroscopic constants were derived for each of the species. These new sets of spectroscopic constants enable us to predict reliably the rotational spectrum (lines frequencies and intensities) in the 4-1000 GHz frequency range and for J and Ka up to 80 and 31, respectively. Combined with IRAM 30 m antenna observations of Orion, this experimental study allowed us to detect 15N substituted ethyl cyanide for the first time in Orion. The derived column density and rotational temperature are 10^13 cm-2 and 150 K for the plateau and 3 10^14 cm-2 and 300 K for the hot core. The deuterated species were searched for but were not detected. The upper limit to the column density of each deuterated isotopologues was 10^14 cm-2.

Affiliated with

Also associated with

No associations

Rating

Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Rotational spectrum of deuterated and 15N ethyl cyanides: CH3CHDCN and CH2DCH2CN and of CH3CH2C15N will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-228631