Rotational dependence of Franck-Condon factors for selected band systems of TiO, ZrO, MgO, LaO, and SiO

Astronomy and Astrophysics – Astrophysics

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Astronomical Spectroscopy, Franck-Condon Principle, Molecular Spectra, Transition Probabilities, Molecular Oscillations, Molecular Rotation, Schroedinger Equation

Scientific paper

The perturbed rotating Morse oscillator model is used to calculate the rotational dependence of the Franck-Condon factors of the gamma, gamma-prime, alpha and phi systems of TiO; the gamma, beta, alpha, A, and B systems of ZrO; the green (B-X), red (B-A), and D-A systems of MgO; the A-X and B-X systems of LaO; and the A-X system of SiO. All of these systems except the green and red systems of MgO show significant rotational dependence.

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