Rotational analysis of the ND A 3Πi-X 3Σ- (0,0) band

Computer Science

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Scientific paper

The spectrum of ND was obtained by flash photolysis of DN3 using an 11-m concave grating in Eagle mounting. The A 3Πi-X 3Σ- (0,0) band was analyzed. The low rotational temperature permitted identification of the lines of the satellite branches and of the low J lines of the main branches. Wave numbers, term values, and constants were calculated by digital computers. We give some of the derived constants (cm-1):
Te + G(0)Bλγ × 102Aδ × 102ɛ × 103
X3Σ-0.00 +/- 28.7822 +/- 20.907 +/- 93.03 +/- 4
A3Πi29798.72 +/- 38.7573 +/- 1-34.56 +/- 35.61 +/- 8-9.00 +/- 7

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