Results of a comprehensive study of the photochemistry of N2(+) in the ionosphere

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Atmospheric Chemistry, Ionospheric Ion Density, Nitrogen Ions, Photochemical Reactions, Positive Ions, Atmospheric Models, Ionospheric Sounding, Recombination Reactions, Satellite Sounding, Vertical Distribution

Scientific paper

The improved match that can be obtained between the Atmospheric Explorer (AE) data on the ionospheric F layer N2(+) abundance and theoretical predictions by changing the dissociative recombination rate coefficient is demonstrated. Historically, models have overestimated the N2(+) concentration. It is shown that the calculated enhancement is due to charge exchange between 0(+)(2D) with N2. Increasing alpha by a factor of 2-3, at least in the orbits examined, can augment the destruction of vibrationally excited N2(+) ions. However, the validity of the correction is dependent on the availability of further laboratory data.

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