Recombination of Oxygen Atoms in the Gas Phase

Details Recombination of Oxygen Atoms in the Gas Phase Recombination of Oxygen Atoms in the Gas Phase

Aug 1960

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1960natur.187..686d&link_type=abstract

Nature, Volume 187, Issue 4738, pp. 686-688 (1960).

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Scientific paper

THE rate of gas phase recombination of oxygen atoms at 10° C. in a flow system has been measured. The experimental method was essentially that described by Schiff1. Oxygen atoms were produced from electrolytic gas containing a small percentage of water vapour by passage through a microwave discharge. The decay of oxygen atom concentration along the axis of a cylindrical `Pyrex' tube, 4 cm. in diameter and 100 cm. long, was followed by a movable isothermal probe similar to that used by Schiff1. Linear flow-rates in the range 60-250 cm./sec. and total pressure of 0.3-2 mm. mercury were employed. The initial atom concentration, estimated from the power input to the probe, was of the order 5-10 per cent.

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