Reactions of chlorine nitrate with HCl and H2O

Details Reactions of chlorine nitrate with HCl and H2O Reactions of chlorine nitrate with HCl and H2O

Nov 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986georl..13.1343h&link_type=abstract

Geophysical Research Letters (Supplement) (ISSN 0094-8276), vol. 13, Nov. 1986, p. 1343-1346. NASA-supported research.

Other

4

Atmospheric Chemistry, Hydrochloric Acid, Inorganic Nitrates, Photolysis, Water, Adsorption, Fourier Transformation, Infrared Spectrophotometers, Ozone, Reaction Kinetics

Scientific paper

The kinetics of the reactions of chlorine nitrate with HCl and H2O are characterized using a static photolysis/Fourier transform infrared spectrophotometer apparatus. For the homogeneous gas-phase reaction with HCl, an upper limit for the rate constant of less than 8.4 x 10 to the -21st, and for the reaction with H2O, a limit of less than 3.4 x 10 to the -21st cu cm/molecule per s, were obtained at 296 + or - 2 K. The yield of HNO3 is almost unity in both cases, and no synergistic effect is noted between HCl and H2O. The kinetic behavior of the reaction with H2O is well described by simple first-order kinetics, while the behavior of the reaction with HCl is described in terms of the Langmuir adsorption isotherm.

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