Rate Constants for the Reactions of Hydroxyl and Hydroperoxyl Radicals with Ozone

Details Rate Constants for the Reactions of Hydroxyl and Hydroperoxyl Radicals with Ozone Rate Constants for the Reactions of Hydroxyl and Hydroperoxyl Radicals with Ozone

May 1973

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1973sci...180..735d&link_type=abstract

Science, Volume 180, Issue 4087, pp. 735-737

Computer Science

5

Scientific paper

Chain decomposition of ozone by hydroxyl and hydroperoxyl radicals has been observed. The rate constant at 300^circK for OH + O3-> HO2 + O2 is 8 × 10-14 cubic centimeters per second. The rate constant for HO2 + O3-> OH + 2O2 is 3 × 10-15 cubic centimeters per second. These results have implications concerning stratospheric ozone.

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