Raman Spectra of Compounds with Three Benzene Rings

Details Raman Spectra of Compounds with Three Benzene Rings Raman Spectra of Compounds with Three Benzene Rings

Sep 1938

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1938natur.142..477m&link_type=abstract

Nature, Volume 142, Issue 3593, pp. 477 (1938).

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Scientific paper

IN this investigation we have succeeded for the first time in obtaining the Raman spectra of o-diphenyl benzene and m-diphenyl benzene. We have studied these compounds with the view of obtaining some evidence about the nature and symmetry of their benzene rings and also to record their Raman lines and to assign their frequencies correctly. These two substances are solid at the ordinary temperature and they present the difficulty of showing such powerful fluorescence under the total radiation of the mercury arc that the Raman lines are almost all completely masked, leaving scarcely any trace of such lines on the plate. Using these substances in the molten state and taking other great precautions, we have been able to suppress, as the accompanying photographs show, a good deal of the continuous fluorescent background, which was found to be even more marked in the case of m-diphenyl benzene.

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