Raman Effect in Metallic Halides.

Details Raman Effect in Metallic Halides. Raman Effect in Metallic Halides.

Jun 1930

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1930natur.125..892k&link_type=abstract

Nature, Volume 125, Issue 3163, pp. 892 (1930).

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IT is known that the crystalline halides of the alkali metals (for example, rock-salt) fail to exhibit the Raman effect. With the view of elucidating the reason for this behaviour, I was led to examine a series of other crystalline metallic halides, using the technique described in a recent note (NATURE, Mar. 22, p. 463). Amongst the numerous solids examined, the two chlorides of mercury stand out conspicuously, giving Raman lines of great intensity corresponding to both positive and negative shifts of frequency (Figs. 1 (a) and (b), lines marked with arrow, the exciting line being 4358 A.).

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