Raman and Infra-Red Spectra of Germanium Tetrafluoride

Details Raman and Infra-Red Spectra of Germanium Tetrafluoride Raman and Infra-Red Spectra of Germanium Tetrafluoride

Sep 1951

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1951natur.168..557c&link_type=abstract

Nature, Volume 168, Issue 4274, pp. 557 (1951).

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Scientific paper

THE Raman spectrum of gaseous germanium tetrafluoride at 1.8 atm. has been investigated with mercury arc excitation, and two lines have been observed. One is excited by λ 4358 and the other by λ 4046 A., the measured Δν-values being 737.1 and 738.4 cm.-1 respectively. This shift may with confidence be identified with the symmetrical breathing frequency of the tetrahedral GeF4 molecule, to which we assign the value ν1 = 738 +/- 2 cm.-1.

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