Radiative lifetimes of the second negative system of O2(+)

Computer Science

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Electron Transitions, Internuclear Properties, Oxygen Ions, Radiative Lifetime, Absorption Spectra, Emission Spectra, Molecular Ions, Spontaneous Emission, Transition Probabilities

Scientific paper

The dipole moment of the A2Pi(u)-X2Pi(g) transition of O2(+) is calculated as a function of internuclear distance using ab initio methods. The band absorption oscillator strengths and band transition probabilities of the second negative system are derived and the resulting lifetimes are compared with experimental data. The high-lying v double prime levels of the ground state may decay into low-lying v prime levels of the excited state. The corresponding radiative lifetimes are calculated.

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