Radiative association of CH3(+) and H2

Details Radiative association of CH3(+) and H2 Radiative association of CH3(+) and H2

Nov 1985

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1985apj...298..382b&link_type=abstract

Astrophysical Journal, Part 1 (ISSN 0004-637X), vol. 298, Nov. 1, 1985, p. 382-386.

Mathematics

Probability

13

Association Reactions, Hydrogen Clouds, Interstellar Chemistry, Nuclear Spin, Radiative Recombination, Reaction Kinetics, Electron Transitions, Langevin Formula, Methyl Compounds

Scientific paper

The temperature variation of the rate coefficient k1 for CH3++H2→CH5++hν is computed treating the para and ortho forms of H2 separately, taking account of nuclear spin and using an accurate theory of the kinetics of association. The results are made absolute with the aid of the measurement at 13K by Barlow, Dunn, and Schauer. By combining this measurement with the CH5+ vibrational frequencies obtained by Pople from a quantal study, it is deduced that the probability of the stabilizing radiative transition is 5.4.×102s-1.

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