Quantum oscillations: Collisional broadening of Rydberg states by alkali perturbers

Details Quantum oscillations: Collisional broadening of Rydberg states by alkali perturbers Quantum oscillations: Collisional broadening of Rydberg states by alkali perturbers

Apr 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999aipc..467..286h&link_type=abstract

The 14th international conference on spectral line shapes. AIP Conference Proceedings, Volume 467, pp. 286-300 (1999).

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Multiphoton Ionization And Excitation To Highly Excited States, Line And Band Widths, Shapes, And Shifts

Scientific paper

This paper qualitatively and quantitatively develops a theory which allows the calculation of the widths and shifts of the two photon Doppler free transitions from the ground states of alkali atoms to Rydberg n2S and n2D states. The widths and shifts result from collisions between Rydberg atoms and ground state alkali atoms, either of the same of other species. Impact theory calculations of the broadening and shift calculations applied to K**(nS)-K, K**(nS)-Rb, Rb**(nS)-Rb, Rb**(nS)-K show substantial agreement with experiment.

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