Quadruply Bonded M_2 Complexes Incorporating Thienylethynyl and Thienylvinyl Carboxylates

Details Quadruply Bonded M_2 Complexes Incorporating Thienylethynyl and Thienylvinyl Carboxylates Quadruply Bonded M_2 Complexes Incorporating Thienylethynyl and Thienylvinyl Carboxylates

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confetf14r&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Computer Science

Mini-Symposium: Metal Containing Molecules

Scientific paper

Quadruply bonded metal complexes, where M = Mo, W, that incorporate thienylethynyl and thienylvinyl carboxylates are being synthesized. Varying the bond order of the C2 unit between the thienyl group and the carboxylate tether provides a series of complexes in which a comparative study on the electronic delocalization in the ground and excited states can be conducted. The properties of these complexes will be predicted by DFT calculations and probed by steady-state absorbance, emission, electrochemistry, and ns- and fs-transient absorption.

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