Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br)

Details Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br) Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br)

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confemj04k&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Statistics

Computation

Matrix/Condensed Phase

Scientific paper

Halogen atoms are important reactive radicals in the atmosphere, and the reactions of these radicals often proceed through formation of a pre-reactive complex. In this work, pulsed jet discharge matrix isolation spectroscopy and computational methods were used to characterize pre-reactive complexes of halogen atoms with simple halons. Our experiments combined matrix isolation techniques with a pulsed DC discharge nozzle, where a dilute CH2XBr (X=H,Cl,Br):rare gas sample was gently discharged and the products deposited onto a KBr window. The Br--BrCH2X (X=H,Cl,Br) complexes were characterized by infrared and electronic spectroscopy, supported by ab initio and Density Functional Theory (DFT) calculations, which shed light on the structure of, bonding in, and binding energy of the complexes.

Affiliated with

Also associated with

No associations

Rating

Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br) does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br), we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Pulsed Jet Discharge Matrix Isolation and Computational Study of Halogen Atom Complexes: Br--BrCH2X (X=H, Cl, Br) will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-999805