Probability Distribution of Enantiomorphous Forms in Spontaneous Generation of Optically Active Substances

Details Probability Distribution of Enantiomorphous Forms in Spontaneous Generation of Optically Active Substances Probability Distribution of Enantiomorphous Forms in Spontaneous Generation of Optically Active Substances

Dec 1971

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1971sci...174.1018p&link_type=abstract

Science, Volume 174, Issue 4013, pp. 1018-1020

Mathematics

Probability

16

Scientific paper

The crystallization of 1,1'-binaphthyl from its racemic melt is an example of spontaneous generation of optical activity. The distribution of specific rotations in 200 individual samples varied from [α ]D = -218 degrees to [α ]D = +206 degrees with a mean of +0.14 degree and standard deviation of 86.4 degrees. This resolution into enantiomers is determined by chance development, with equal probability, of right- or left-handed crystallites; it can b2 controlled and made stereospecific by addition of dissymmetric compounds at low concentrations.

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