Pressure-induced line shifts in the ν3 band of nitrous oxide perturbed by N2, O2, He, Ar and Xe.

Details Pressure-induced line shifts in the ν3 band of nitrous oxide perturbed by N2, O2, He, Ar and Xe. Pressure-induced line shifts in the ν3 band of nitrous oxide perturbed by N2, O2, He, Ar and Xe.

Jul 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jqsrt..56....1m&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 56, issue 1, pp. 1-16

Computer Science

12

Molecular Processes: Laboratory Spectra

Scientific paper

Pressure-shifting parameters in the ν3 band of N2O are reported for five perturbers: N2, O2, He, Ar, and Xe. They were obtained with two spectrometers built in the authors' laboratory: a Fourier transform spectrometer yielding a 0.5×10-3cm-1atm-1 precision for these parameters, thanks to a precise modelling of its apparatus function, and a TDL spectrometer insuring a 0.2×10-3cm-1atm-1 precision, which permits to check the FT results for a few lines. The experimental values are compared with values computed from a semi-classical model.

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