Pressure broadening of H2O in the (301)←(000) band: effects of angular momentum and close intermolecular interactions.

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Water Vapor: Laboratory Spectra, Water Vapor: Molecular Processes, Water Vapor: Line Broadening

Scientific paper

Two spectroscopic lines of water vapor, broadened by N2, are examined within the complex Robert-Bonamy formalism in an effort to understand their sensitivity to short-range interactions. The two lines, both of which occur in the (301)←(000) band, are compared in terms of their dependence on impact parameter, sensitivity to convergence of the short-range potential, and the symmetry terms of the intermolecular potential.

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