Potential energy curves and dissociation energy of SiCl

Details Potential energy curves and dissociation energy of SiCl Potential energy curves and dissociation energy of SiCl

Jul 1981

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1981jqsrt..26...11v&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 26, July 1981, p. 11-13.

Computer Science

2

Chlorides, Dissociation, Electron States, Ground State, Potential Energy, Silicon Compounds, Diatomic Molecules, Molecular Energy Levels, Molecular Excitation

Scientific paper

The true potential energy curves have been constructed for the ground and excited electronic states of SiCl by the method of Lakshman and Rao (1971). The dissociation energy of the ground state has been estimated by fitting the Hulburt-Hirschfelder function to the true potential energy curves. The dissociation energy thus obtained is 33,500 per cm (4.15 eV), which is in good agreement with the value of 4.5 + or - 0.5 eV reported by Gaydon (1968).

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