Plutonium oxidation state distributions in the Pacific Ocean during 1980-1981

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Scientific paper

The concentration of plutonium and its oxidation state distribution have been measured as a function of depth at three locations in the North Pacific Ocean. Concentration profiles were similar to those observed in the same area during 1974 with primary maxima at depths of a few hundred meters below the surface and secondary maxima near the bottom. Oxidation state distribution profiles were similar at the three locations with plutonium about equally divided between the reduced and oxidized forms except near the bottom. There the oxidized form was more abundant and comprised ~ 90% of the total plutonium. No major change in oxidation state occurred at the depths of the shallow concentration maxima suggesting that their formation and persistence were not dependent upon a redox change. The concentration maxima near the bottom coincided with the enhanced abundance of the poorly sorbed oxidized form suggesting that they resulted from the loss of oxidized plutonium from the sediments.

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