Photochemistry of unsaturated nitriles on Titan

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Nitriles, Organic Chemistry, Photochemical Reactions, Titan, Atmospheric Models, Satellite Atmospheres, Unsaturation (Chemistry), Vapor Phases

Scientific paper

The unsaturated nitrile cyanoacetylene and dicyanoacetylene were observed on Titan by the Voyager 1 mission. Studies in the laboratory of the photochemical reactions of these compounds alone or with another gas present on Titan (acetylene, ethene, hydrogen cyanide, and carbon monoxide) were performed. Trimeric and tetrameric compounds, (1 + 1), (1 + 2), or (2 + 2) adducts were observed depending on the ultraviolet radiation (185, 206, or 254 nm light) and the relative ratio of the two gases. Extrapolation to the atmosphere of Titan is discussed.

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