Computer Science
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confefe01m&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Computer Science
Dynamics
Scientific paper
The photodissociation mechanism of copper (II) chloro complexes in methanol is studied by means of ultrafast broadband time-resolved deep-UV/UV/vis spectroscopy using [CuII(MeOH)_5 Cl]^+ as a model molecule. Upon 255 nm excitation, the majority of [CuII(MeOH)5Cl]+ dissociate to form chlorine atoms Cl. and penthacoordinate copper(I) solvated complexes [CuI(MeOH)5]+, which is followed by recombination back to the parent molecules. A three body-disscoation in which the nascent [CuI(MeOH)5]+ fragment undergoes a methanol-ligand loss is observed to be of minor importance. The solvent influence on the photoreaction will be discussed.
El-Khoury Patrick
Mereshchenko Andrey S.
Pal Soumik
Tarnovsky Alexander N.
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