Petrogenesis of basalts from the project FAMOUS area: experimental study from 0 to 15 kbars

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Tholeiitic basalt glasses from the FAMOUS area of the Mid-Atlantic Ridge are among the most primitive basaltic liquids reported from the ocean basins. One of the more primitive of these [Mg/(Mg + Fe2+) = 0.68; Ni = 232 ppm; TiO2 = 0.61] glasses (572-1-1) was selected for an experimental investigation. This study found olivine to be the liquidus phase from 1 atm to 10.5 kbar where it is replaced by clinopyroxene. The sequence of appearance of phases at 1 atm pressure is olivine (1268°C), plagioclase (1235°C) and clinopyroxene (1135°C). The sample is multiply saturated at 10.5 kbar with olivine (Fo88), clinopyroxene (Wo32En60Fs9), and orthopyroxene (Wo5En83Fs12). From the 1-atm data we have measured (FeO/MgO) olivine/(FeO*/MgO) liquid (K'D) for olivine-melt pairs equilibrated at 12 temperatures in the range 1268-1205°C. K'D varies from 0.30 at 1205°C to 0.27 at 1268°C. Analysis of high-pressure olivine melt pairs indicates a systematic increase in K'D with pressure. Evaluation of the 1-atm experiments reveals that fractionation of olivine followed by olivine + plagioclase can generate much of the variation in major element chemistry observed in the FAMOUS basalt glasses. However, it cannot account for the entire spectrum of glass compositions - particularly with respect to TiO2 and Na2O. The variations in these components are such as to require different primary liquids. Comparison of clinopyroxene microphenocrysts/xenocrysts found in oceanic tholeiites with experimental clinopyroxenes reveal that the majority of those in the tholeiites may have crystallized from the magma at pressures greater than ~ 10 kbar and are not accidental xenocrysts. Clinopyroxene fractionation at high pressures may be a viable mechanism for fractionating basaltic magmas. The major and minor element mineral/melt K'd's from our experiments have been used to model the source region residual mineralogy for given percentages of partial melting. These data suggest that ~20% partial melting of a lherzolite source containing 0-10% clinopyroxene can generate the major and minor element concentrations in the parental magmas of the Project FAMOUS basalt glasses.

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